全文获取类型
收费全文 | 1375篇 |
免费 | 23篇 |
国内免费 | 4篇 |
专业分类
化学 | 948篇 |
晶体学 | 6篇 |
力学 | 14篇 |
数学 | 296篇 |
物理学 | 138篇 |
出版年
2019年 | 8篇 |
2017年 | 11篇 |
2016年 | 27篇 |
2015年 | 20篇 |
2014年 | 25篇 |
2013年 | 51篇 |
2012年 | 53篇 |
2011年 | 75篇 |
2010年 | 43篇 |
2009年 | 24篇 |
2008年 | 48篇 |
2007年 | 66篇 |
2006年 | 51篇 |
2005年 | 53篇 |
2004年 | 45篇 |
2003年 | 33篇 |
2002年 | 50篇 |
2001年 | 32篇 |
2000年 | 18篇 |
1999年 | 25篇 |
1998年 | 18篇 |
1997年 | 8篇 |
1996年 | 23篇 |
1995年 | 16篇 |
1994年 | 27篇 |
1993年 | 23篇 |
1992年 | 20篇 |
1991年 | 15篇 |
1990年 | 24篇 |
1989年 | 14篇 |
1988年 | 9篇 |
1987年 | 11篇 |
1986年 | 10篇 |
1985年 | 25篇 |
1984年 | 26篇 |
1983年 | 12篇 |
1982年 | 31篇 |
1981年 | 19篇 |
1980年 | 15篇 |
1979年 | 18篇 |
1978年 | 21篇 |
1977年 | 12篇 |
1976年 | 20篇 |
1975年 | 14篇 |
1974年 | 8篇 |
1973年 | 10篇 |
1972年 | 7篇 |
1971年 | 10篇 |
1928年 | 6篇 |
1926年 | 6篇 |
排序方式: 共有1402条查询结果,搜索用时 328 毫秒
11.
Lothar Berg 《Aequationes Mathematicae》1990,40(1):44-53
Summary A certain class of entire functionsF(s) of order zero which are asymptotically equal to the sum of just two neighbouring terms of their power series when |s| with |args| < – for any fixed > 0, is investigated. Which two terms one has to take, depends upons. It is shown that these functions have infinitely many negative zeros, and the asymptotic behaviour of the zeros is also determined. 相似文献
12.
Feng Jiang Lothar Lilge Bradley Logie Yi Li Michael Chopp 《Photochemistry and photobiology》1997,65(4):701-706
Abstract— The effect of Photofrin encapsulated in a liposome delivery vehicle for photodynamic therapy (PDT) of the 9L gliosarcoma and normal rat brain was tested. We hypothesized that the liposome vehicle enhances therapeutic efficacy, possibly by increasing tumor tissue concentration of Photofrin. Male Fisher rats bearing a 9L gliosarcoma were treated 16 days after intracerebral tumor implantation with either Photofrin in dextrose (n = 5) or Photofrin in liposome (n = 6). Nontumor-bearing animals were treated with Photofrin delivered either in dextrose (n = 4) or liposome (n = 4) vehicle. Tissue concentrations of Photofrin delivered either in dextrose (n = 4) or liposome (n = 4) vehicle were measured in tumor, brain adjacent to tumor and in normal brain tissue. Photofrin was administered (intraperitoneally) at a dose of 12.5 mg/kg and PDT (17 J/cm2 of 632 nm light at 100 mW/cm2 ) was performed 24 h after Photofrin administration. Brains were removed 24 h after PDT and stained with hematoxylin and eosin for analysis of cellular damage. The PDT using Photofrin in the liposome vehicle caused significantly more damage to the tumor ( P < 0.001) than did PDT with Photofrin in dextrose. The PDT of tumor with Photofrin delivered in liposomes caused a 22% volume of cellular necrosis, while PDT of tumor with Photofrin delivered in dextrose caused only scattered cellular damage. Photofrin concentration in tumors was significantly higher ( P = 0.021) using liposome (33.8 ± 18.9 μg/g) compared to dextrose delivery (5.5 ± 1.5 μg/g). Normal brain was affected similarly in both groups, with only scattered cellular necrosis. Our data suggest that the liposome vehicle enhances the therapeutic efficacy of PDT treatment of 9L tumors. 相似文献
13.
14.
Synthesis and Crystal Structure Determination of Lead(II) Oxide Halide Alcoholates with Different Connectivity of Pb4O4 Heterocubane‐like Subunits The reaction of red lead(II) oxide (Litharge) and lead(II) halide (Cl? and Br?) with diethylene glycole at a temperature of 180 °C leads to the isotypic compounds [Pb6(C4H8O3)O2Cl6] (1) and [Pb6(C4H8O3)O2Br6] (2) . In a similar synthesis with PbI2 as educt at temperature of 160 °C the two modifications β‐[Pb6(C4H8O3)O2I6] (3) and α‐[Pb6(C4H8O3)O2I6] (4) were found, whereas at a reaction temperature of 180 °C [Pb9(C2H4O2)(C4H8O3)O3I8] (5) was surprisingly obtained as product. The X‐ray diffraction data show that at a temperature of 180 °C a splitting of the ether took place. The cited compounds show cubane like subunits built by lead and oxygen atoms. These fragments are connected by alkoholate molecules. In 5 additionally an I6 octahedra centered by lead is observed. 相似文献
15.
16.
Pd/P(t-Bu)(3) serves as an unusually reactive catalyst for Stille reactions of aryl chlorides and bromides, providing solutions to a number of long-standing challenges. An unprecedented array of aryl chlorides can be cross-coupled with a range of organotin reagents, including SnBu(4). Very hindered biaryls (e.g., tetra-ortho-substituted) can be synthesized, and aryl chlorides can be coupled in the presence of aryl triflates. The method is user-friendly, since a commercially available complex, Pd(P(t-Bu)(3))(2), is effective. Pd/P(t-Bu)(3) also functions as an active catalyst for Stille reactions of aryl bromides, furnishing the first general method for room-temperature cross-couplings. 相似文献
17.
Natural irones from the essential oil of Iris rhizomes develop by oxidative degradation of C31-triterpenoids produced by the plant. Two enantiomeric forms of irones are found in Iris, oils of different origin. The optical properties and CD spectra of irones, dihydroirones and their C31-precursors are reported and their absolute stereochemistry is determined. 相似文献
18.
Comparison between capillary electrophoresis and ion-chromatography for analysis of inorganic anions
Separation and detection of some selected inorganic anions with capillary electrophoresis are shown. The anions are separated in microbore capillaries (25 m* 0.2 m) and detected with a UV-detector. Results are compared with the method of ion exchange chromatography. In consideration of the most important physical and chemical parameters an easy kind of computer simulation for such electropherograms was developed.To get optimal results of separation and UV-detection in capillary electrophoresis some parameters of the device HPE 100, i.e. loading time in the electrokinetic sample injection mode and the running voltage are varied. The behaviour of absorption in the UV region of the chosen anions as well as the influence of pH values in retention behaviour are investigated. There is a simple way to calculate the electrophoretic mobilities from known retention times. Approximate limits of detection for all anions and for each technique are given. 相似文献
19.
Alexander S GolubevNatalia N Sergeeva Lothar HennigAlexey F Kolomiets Klaus Burger 《Tetrahedron》2003,59(9):1389-1394
An efficient synthesis of trifluoromethyl-containing 2,3-allenols via carbonyl-yne reaction of 3,3,3-trifluoropyruvates with acetylenes is described. In the presence of MgBr2·Et2O the reaction of methyl trifluoropyruvate with hex-1-yne proceeds diastereoselectively. Trifluoromethyl-substituted 2,3-allenols can be stereoselectively transformed into trifluoromethyl-substituted 2,5-dihydrofurans on treatment with AgNO3. 相似文献
20.
Boca R Gembický M Herchel R Haase W Jäger L Wagner C Ehrenberg H Fuess H 《Inorganic chemistry》2003,42(22):6965-6967
Triethylenetetramine (L(4)) was used as a tetradentate blocking ligand that, after complexation with Ni(II), leaves two sites ready for ligation with tricyanomethanide. The formed binuclear complex [L(4)Ni(NCC(CN)CN)(2)NiL(4)](ClO(4))(2) exhibits a ferromagnetic coupling with J/hc = +0.15 cm(-1) and g(Ni) = 2.126; below 16 K, a ferromagnetic ordering is evidenced by ac magnetic susceptibility (both in-phase and out-of-phase), magnetization, field-cooled magnetization, and zero-field-cooled magnetization measurements. 相似文献